Synthesis and reactivity of a 9-membered azaenediyne: importance of proximity effect in N-alkylation.
نویسندگان
چکیده
Synthesis of a 9-membered azaenediyne has been achieved for the first time via intramolecular N-alkylation; the importance of proximity of the reacting centres via cobalt carbonyl complexation of the acetylenic moiety and not the activation of propargylic carbon has been demonstrated.
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ورودعنوان ژورنال:
- Chemical communications
دوره 15 شماره
صفحات -
تاریخ انتشار 2006